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Did you know that Diet Coke has more caffeine in it? So regular Coke and Coke Zero has 34 milligrams of caffeine. Whereas Diet Coke has 46 milligrams. So for context, a standard cup of coffee has 90 milligrams. So Diet Coke still has half the caffeine of a coffee. That explains the 3pm ciggy, girlies are partaking in.